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To add an item, simply assign a value to a key the dictionary does not have yet:

Example

Prompt
Write a Python program that creates a dictionary called thisdict with keys "brand", "model", and "year" with values "Ford", "Mustang", and 1964. Then add a new key "color" with value "red" and print the dictionary.
Output: complete Python program

Update Dictionary

Calling update() merges the items of its argument into the dictionary, creating any item that is not there yet.

That argument has to be either a dictionary or an iterable object made up of key:value pairs.

Example

Use update() to give the dictionary a new color item:

Prompt
Write a Python program that creates a dictionary called thisdict with keys "brand", "model", and "year" with values "Ford", "Mustang", and 1964. Then add a new key "color" with value "red" using the update() method and print the dictionary.
Output: complete Python program